Jim, no it will not. 32NAA is a specialty necked down cartridge and requires a specific barrel chamber (it will no work in a 32ACP Pistol). ---- google.com/search?q=32NAA&source=lnms&tbm=isch&sa=X&ved=0ahUKEwiLp5WpuqjgAhWKmeAKHTo7D2MQ_AUIDygC&biw=1280&bih=618#imgrc=8HDBfIiTcFjIxM:

No, it will not safely chamber. Only use ammunition of the same caliber your firearm is marked for. They may both be .32 caliber cartriges, but they are entirely different. For example, you wouldn't try to chamber a .280 remington in a rifle chambered 7mm mag right?

No, Jim, those letters after the "32" have some specific meaning ... and if one ignored that and tries to interchange these two cartridges .. one very quickly understands the significance of the letters. Please don;t even try it.

no it is a totally different round and will not work and will be unsafe